By default, the Quick Access Toolbar contains a set of 3 commands such as Save, Undo, and Redo.

Click on the Drop-down arrow of the Quick Access Toolbar (Customize Quick Access Toolbar) as shown in the first step of the picture below.

Then select one of the Commands you want to add Look at the newly added command in the step 3 of the picture given below.

Click on the drop-down arrow of the (Customize) Quick Access Toolbar Then click on the More Commands.

Or use Ribbon Display Options icon which you can see on the top right corner of the title bar.

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It is a customizable toolbar that comes with a set of independent commands.

It gives you quick access to commonly used commands such as Save, Undo, Redo, etc.

With a left click you can add any of these commands to Quick Access Toolbar.

The indent, spacing values, individual styles and other features that appear on the ribbon cannot be added to quick access toolbar.

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Word 2016 Quick Access Toolbar